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Hydrogenation and Margarine


Jump within page to Definition of the hydrogenation process
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Hydrogenation:

Definition: Hydrogenation is the process of forcing hydrogen atoms into the holes of unsaturated fatty acids. This is done with hydrogen gas under pressure with a metal catalyst at a temperature of 248-410 degrees F (120-210 C).
Hydrogenized Fatty  Acid Molecule
100% Hydrogenation: The above illustration shows how Alpha-Linolenic Acid looks completely hydrogenated. The red H's show where the holes in the molecule were before the hydrogenation process was started. Notice all the holes are filled. This now has the same configuration as Stearic Acid! (But there is a slight difference: This converted fatty acid now has trace elements in it from the hydrogenation process catalyst.) It has also straightened out. Its melting point has changed from 10 degrees F (-12 C) to that of Stearic Acid, 158 degrees F (158 C). For all practical purposes it is Stearic Acid and isn't any worse for you. If the manufacturers produced margarine and shortening in this way there would be fewer problems. You see, saturated fatty acids have no room in them for shifted bonds or hydrogen atoms in the trans- configuration. That requires holes. But unfortunately, Stearic Acid is just too hard a fat to be made into margarine or shortening.


Partially hydrogenated fats           (Top of page)

Not too hard - not too soft... Of course, vegetable oil is too soft for margarine or shortening because it is liquid. Saturated fat is too hard. Margarine requires something in the middle. And here is where the problem lies. Margarine and shortening makers `partially hydrogenate' their product. They only add hydrogen atoms until the oil is at the desired consistency. For our health this does terrible things.

Matter unorganized: During the hydrogenation process, hydrogen atoms are inserted in no particular order. (Nature does it in a very controlled way.) When they stop the incomplete hydrogenation process, unsaturated fatty acids are in varying stages of hydrogenation. Some molecules are mostly hydrogenated, while others are not. And the double bonds have often shifted to unnatural positions. Each molecule can be in varying cis-/trans- configurations. Mr. Erasmus has stated, "So many different compounds can be made during partial hydrogenation that they stagger the imagination. Scientists have barely scratched the surface of studying changes induced in fats and oils by partial hydrogenation."1 The end result is many of these altered substances are toxic to our systems. One study has shown up to 60% trans- fatty acid content was found in some margarine, with less than 5% essential fatty acids remaining. (This was healthy oil before they started processing it!) The average trans- fatty acid content of stick margarine made in this way is 31% with a range of 9.9 to 47.8%.


References:
1. Fats that Heal and Fats that Kill pg. 103


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Al Durtschi, E-mail: mark@waltonfeed.com

Home Page: http://waltonfeed.com/

Much of the information for the EFA pages was taken from Fats that Heal Fats that Kill by Udo Erasmus, Published by Alive Books, Burnaby, BC, Canada 1-800-661-0303

All contents copyright (C) 1995, Al Durtschi. All rights reserved.
Revised: 19 June 00